By Ilya Prigogine
The Advances in Chemical Physics sequence presents the chemical physics and actual chemistry fields with a discussion board for severe, authoritative reviews of advances in each sector of the self-discipline. packed with state-of-the-art examine said in a cohesive demeanour no longer discovered somewhere else within the literature, each one quantity of the Advances in Chemical Physics sequence serves because the excellent complement to any complex graduate classification dedicated to the research of chemical physics.
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The molecular constitution hypothesis--that a molecule is a set of atoms associated by way of a community of bonds-- offers the important technique of ordering and classifying observations in chemistry. although this speculation isn't really comparable on to the physics which governs the motions of atomic nuclei and electrons.
Prof. Dr. -Ing. Reinhard Seeling - Rheinisch-Westfälische Technische Hochschule Aachen
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7. K. J. Laidler and J. C. Polanyi, in Progress in Reaction Kinetics, Ed. G. Porter, Pergamon Press, Oxford, 1965. 8. J. C. Light, Disc. , 44, 14 (1967). 9. (a) J. C. Polanyi and S. D. Rosner, J. Chem. Phys. 38, 1028 (1963); (b) P. J. Kuntz, E. M. Nerneth, J. C. Polanyi, S. D. Rosner, and C. E. Young, J. Chem. Phys. 44, 1168 (1966); (c) K. G. Anlauf, J. C. Polanyi, W. H. Wong, and K. B. Woodall, J. Chem. Phys. 49, 5189 (1968); (d) P. J. Kuntz, E. M. Nemeth, and J. C. Polanyi, J. Chem. Phys. 50, 4607 (1969); (e) P.
In those days, mass spectrometers were used mainly by experimental physicists who were concerned primarily with mass determination and isotope analysis. It~ is this latter aspect which has occupied many chemical physicists for the past two decades and with which we are here concerned. Nonetheless, a great deal of gaseous ion chemistry, treated from the other standpoint, is to be found in reports of these studies, and if included in this review would inflate considerably our one-paper-a-year rate.
Channels of Reaction . . . 1. Introduction . . . 2. Single Source and Tandem Mass Spectrometer Techniques 3. High Pressure Mass Spectrometry . 4. Ion Cyclotron Resonance Spectroscopy . . 5. “Exotic” Channels of Reaction . . . References . . . . . . . . . . . , . . . . . . . . . . . . 92 95 97 97 99 102 102 103 105 109 109 111 111 112 114 118 123 123 123 125 126 129 132 I. INTRODUCTION The contribution of ion-molecule reactions to the publication explosion is shown in Figure 1 which illustrates the exponential increase in number of papers published in this field during the past two decades.
Advances in Chemical Physics, Volume 19 by Ilya Prigogine