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By Boschke F.L.

ISBN-10: 3540076050

ISBN-13: 9783540076056

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If r is the electric potential, and r its value at the test site the interaction energy with a chiral system specified by electric charge q and dipole, quadrupole and higher moments p~, Q*I.. 18) the sum is taken over repeated indices. The field sources are fixed in position but the test system is not constrained. 10). It is again found that the lowest order term showing discrimination is that in (kT) -9" and under conditions of realistic fields and electric moments is extremely small in magnitude.

Chem. 8, 227 (1958). Chedd, G. : New Scientist 62, 299 (1974). Craig, D. , Power, E. , T h i r u n a m a c h a n d r a n , T. : Proc. Roy. Soc. (London), Ser. A 322, 165 (1971). Craig, D. , Stiles, P. : Proz. Roy. Soz. (London), Ser. A 343, I I (1971}. Craig, D. , Schipper, E. : Chem. Phys. Letters 25, 476 (1974). Craig, D. , Schipper, E. : Proc. Roy. Soc. (London), Ser.

I t is however possible to proceed in the same w a y as we have done in dealing with the discriminating interactions of extended helical polymers. There is of course the possibility of dealing with optically active solids of this class as if they were giant molecules. 33 D. P. Craig and D. P, Mellor III. D i s c r i m i n a t i o n in the Dispersion Interaction 1. General D e s c r i p t i o n Mavroyannis and Stephen (1962) considered the dispersion interaction in a general framework including radiative corrections.

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Bonding Structure by Boschke F.L.


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