By Gregg J. Lumetta, Robin D. Rogers, Aravamudan S. Gopalan
Content material: Calixarenes for separations / C. David Gutsche -- pt. 1. Calizarene-cation finishing touch -- Extraction of cesium through calixarene-crown-6: from synthesis to procedure / J.-F. Dozol -- improvement of method chemistry for the removing of cesium from acidic nuclear waste through calixarene-crown-6 ethers / Peter V. Bonnesen -- Radiation balance of calixarene-based solvent approach / R.A. Peterson -- habit of calixarene-bis-crown-6 below irradiation: electrospray-mass spectrometry research and molecular dynamics simulations on Cs+ and Na+ complexes of a degradation compound / V. Lamare -- Interfacial good points of assisted liquid-liquid extraction of uranyl and cesium salts: a molecular dynamics research / M. Baaden -- Benzyl phenol derivatives: extraction homes of calixarene fragments / Laetitia H. Delmau -- Calixarene-containing extraction blend for the mixed extraction of Cs, Sr, Pu, and Am from alkaline radioactive wastes / Igor V. Smirnov -- Calixarenes with a unique proton-ionizable workforce: synthesis and steel ion separations / Richard A. Bartsch -- Separations of sentimental heavy-metal cations via decrease rim-functionalized calixarenes / Galina G. Talanova -- CMPO-substituted calixarenes / Volker Böhmer -- Binding of lanthanides(III) and thorium(IV) by way of phosphorylated calixarenes / F. Arnaud-Neu -- Lanthanide calixarene complexes investigated through NMR / B. Lambert -- Bimetallic lanthanide supramolecular edifices with calixarenes / Jean-Claude G. Bünzli -- Molecular popularity via azacalixarenes / Philip D. Hampton -- steel ion complexation and extraction habit of a few acyclic analogs or tert-butyl-calixarene hydroxamate extractants / Timothy N. Lambert -- Calixarenes as ligands in environmentally-benign liquid-liquid extraction media: aqueous biphasic structures and room tempature ionic drinks / Ann E. Visser -- pt. 2. Calixarene-anion complexation -- Calixpyrrole-functionalized silica gels: novel helps for the HPLC-based separation of anions / Jonathan L. Sessler -- decrease rim amide- and amine-substituted calixarenes as section move extractants for oxyions among an aqueous and an natural part / H. Fred Koch -- pt. three. Calixarene compexation of impartial molecules -- Deep cavities and drugs / Dmitry M. Rudkevich -- Calixarene metalloreceptors: demonstration of measurement and form selectivity inside of a calixarene hollow space / Stephen J. Loeb -- Synthesis and structural research of thiacalixarene derivatives / Mir Wais Hosseini -- Synthesis and fullerene complexation reviews of p-allycalixarenes / Charles G. Gibbs -- Hydrogen-bonded cavities dependent upon resorcinarenes by means of layout / Leonard R. MacGillivray
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Extra info for Calixarenes for Separations
A . Peterson, C. L. Crawford, F. F. Fondeur, and T. L. ch004 Westinghouse Savannah River Company, Aiken, SC 29808 The Savannah River Site recently evaluated four alternatives for processing the cesium rich High Level Waste stream at the Savannah River Site. One of the selected process uses a calixarene -basedsolvent extraction process to recover the cesium and produces a purified, lower volume acidic stream for vitrification. Previous work provided limited understanding of the stability of the solvent used in the process in radiation fields.
G . ; McElwee, M . ; Wasserman, M . ; Vandegrift, G . F. , 1992. 22. Leonard, R. ; Chamberlain, D. ; Conner, C. Sep. Sci. Technol. 1997, 32, 193. 23. Leonard, R. ; Liberatore, M. ; Bonnesen, P. ; Presley, D . ; Moyer, Β. ; Lumetta, G . , Sep. Sci. Technol. 1999, 34, 1043. 24. Sachleben, R. ; Bonnesen, P. V . ; Haverlock, T. ; Moyer, B . A. Solvent Extr. Ion Exch. (1999, in press). 25. Lamare, V . ; Eur. J. Org. Chem. 1998, 8, 1559. 26. Law, J. ; Wood, D . ; Herbst, R. S. Sep. Sci. Technol. 1997, 32, 223.
9 M free hydroxide present in the Savannah River simulant), the Cs-3 modifier did not. 26 M ) present in the I N E E L waste simulant, but that 1 did not, instead becoming nitrated at an unacceptably fast rate. A n explanation of the factors contributing to nitration susceptibility, along with an evaluation of calixarene-crown ethers and process solvents that promise to be suitable for an acid-side cesium extraction process, is presented below. Experimental Materials A l l salts and solvents were reagent grade and were used as received, except trioctyl amine, which was distilled prior to use.
Calixarenes for Separations by Gregg J. Lumetta, Robin D. Rogers, Aravamudan S. Gopalan